Reactions of Aryl Acetates with Secondary Alicyclic Amines in Ethanol/Water Mixtures: Effect of the Solvent Composition on the Kinetics and Mechanism

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Reactions of aryl acetates with secondary alicyclic amines in ethanolwater mixtures Effect of the solvent composition on the kinetics a.pdf (147.22 KB)

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2011

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Artículo

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Artículos Medicina y Ciencias de la Salud

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http://hdl.handle.net/11447/882
 http://dx.doi.org/10.1002/kin.20598

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Abstract

We report a kinetic study on the reactions of secondary alicyclic amines toward 4-nitrophenyl, 2,4-dinitrophenyl, and 2,4,6-trinitrophenyl acetates (1, 2, and 3) in ethanol/water mixtures of different...

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Citation

International Journal of Chemical Kinetics, 2011, vol. 43, n° 12, p. 687-693

Keywords

Structure-reactivity correlations , X-Substituted benzoates , 2,4,6-Trinitrophenyl methyl carbonate , Rate-determining step , Aqueous-ethanol , 2,4-Dinitrophenyl acetate , Ester aminolysis , Phenyl carbonate , Nonleaving group , Pyridinolysis

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