Experimental Analyses Emphasize the Stability of the Meisenheimer Complex in a S N Ar Reaction Toward Trends in Reaction Pathways

dc.contributor.author	Campodónico, Paola
dc.contributor.author	Olivares, Belén
dc.contributor.author	Tapia, Ricardo A.
dc.date.accessioned	2021-07-21T16:37:21Z
dc.date.available	2021-07-21T16:37:21Z
dc.date.issued	2020-07
dc.description.abstract	The mechanism of SNAr reactions between 2-chloro-5-nitropyrimidine with primary and secondary alicyclic amines, respectively, have been studied by kinetic measurements. The kinetic data obtained in aqueous media opens a controversial discussion based on Brönsted-type plots analysis. The first approach based on the kinetic data reveals a non-catalyzed pathway. Then, the subtlety of the mathematical treatment of the kinetic data is discussed over a concerted or stepwise mechanism, respectively.	es
dc.identifier.citation	Frontiers in Chemistry, 2020 Jul, vol.8: 583	es
dc.identifier.uri	https://doi.org/10.3389/fchem.2020.00583	es
dc.identifier.uri	http://hdl.handle.net/11447/4188
dc.language.iso	en	es
dc.subject	Brönsted-type plots	es
dc.subject	Meisenheimer complex	es
dc.subject	SNAr reaction	es
dc.subject	Border mechanisms	es
dc.subject	Reaction mechanism	es
dc.title	Experimental Analyses Emphasize the Stability of the Meisenheimer Complex in a S N Ar Reaction Toward Trends in Reaction Pathways	es
dc.type	Article	es

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